Anionic oxidative polymerization: the synthesis of poly(phenylenedicyanovinylene) (PPCN2V).
نویسندگان
چکیده
A new polymerization technique that allows for the first-ever synthesis of poly(phenylenedicyanovinylene)s (PPCN2Vs) is described. PPCN2Vs, with their high electron affinities and structural versatility, seem ideally suited to address the need for new n-type polymers. Remarkably the polymers presented herein become more photoluminescent, in the thin film, under continuous irradiation.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 131 1 شماره
صفحات -
تاریخ انتشار 2009